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Rhodium(I) metallacycles based on alkylated-PTA scaffolds: Synthesis and evaluation as hydroformylation catalyst precursors

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posted on 2020-05-05, 08:08 authored by Diteboho S. Ramaroua, Banothile C. E. Makhubela, Gregory S. Smith
A series of rhodium(I) metallacycles based on alkylated PTA complexes were synthesised and fully characterised
using a range of spectroscopic and analytical techniques. These mononuclear Rh(I) complexes were evaluated in
the aqueous biphasic (water-toluene) hydroformylation of 1-octene, showing chemoselectivity to aldehydes

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University of Cape Town (UCT) and University of Johannesburg (UJ)

NRF-DST Centre of Excellence in Catalysis – c*change and the Harry Crossley foundation

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Keywords

MetallacyclesRhodiumHydroformylationAlkylated-PTAOrganometallic Chemistry

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CC BY 4.0

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